Ann MacIntosh

Degrees, Licensures and Certifications: B.S. - Chemistry, Ithaca College; Ph.D. - Chemistry, Michigan State University

Research Interests: Analysis of Coal and Coal Combustion By-Products using ICP and SEM/EDS. Photochemistry of inorganic complexes for preparation of new compounds and discovery of novel reaction pathways. Application of coordination chemistry and spectroscopic methods to art historical problems. Utilization of Raman and electronic spectroscopies to identify the photodegradation products of artists’ pigments.

Selected Publications

• “Linking Multiple Bonds between Metal Atoms: Clusters Dimers of “Dimers” and Higher Ordered Assemblies” Chisholm, M.H.; Macintosh, A.M. Chem. Rev. 2005, 105, 2949-2976.
• “Oxalate-Bridged Complexes of Dimolybdenum and Ditungsten Supported by Pivalate Ligands: (tBuCO2)3M2(?-O2C2O2)M2(O2CtBu) 3 Correlation of the Solid State, Molecular and Electronic Structures with Raman, Resonance Raman and Electronic Spectral Data”. Bursten, B.E.; Chisholm, M.H.; Clark, R.J.H.; Firth, S.; Hadad, C.M.; Macintosh, A.M.; Wilson, P.J; Woodward, P.M.; Zaleski, J.M. J. Am. Chem. Soc. 2002, 114, 3050.
• “Heterogeneous Electron Transfer Rate Constants for M2(O2CR)40/+, where M = Mo, W, Rh and Ru and R = Alkyl or Aryl” Chisholm, M.H.; Glasgow, K.C.; Klein, L.J.; Macintosh, A.M.; Peters, D.G. Inorg. Chem. 2000, 39, 4354.
• “d3-d3-Diolates of dimolybdenum and ditungsten. 4. Molybdenum Derivatives of S(-)-1,1-Diphenyl-1,2-propanediol, S(-)-1,1,2-triphenyl-1,2-ethanediol and (1R)(2R)-(-)-1,2-Dicyclohexyl-1,2-ethanediol” Chisholm, M.H.; Folting, K.; Huffman, J.C.; Li, H.; Macintosh, A.M.; Wu, D. Polyhedron 2000, 19, 375.
• “Dimolybdenum bis(S,S,S-triisopropoxyamine). A blue compound with an unusual Mo-Mo trip bond” Chisholm, M. H.; Macintosh, A. M.; Huffman, J. C.; Wu, D.-D.; Davidson, E. R.; Clark, R. J. H.; Firth, S. Inorg. Chem. 2000, 39, 3544.
• “Compounds in Which the Mo24+ Unit Is Embraced by One, Two or Three Formamidinate Ligands Together with Acetonitrile Ligands” Chisholm, M.H.; Cotton, F.A.; Daniels, L.M.; Folting, K. Huffmann, J.C.; Iyer, S.S. Lin, C.; Macintosh, A.M.; Murillo, C.A. J. Chem. Soc. Dalton Trans. 1999, 1387.
• “On the Mechanism of Carboxylate Ligand Scrambling at Mo24+ Centers: Evidence for a Catalyzed Mechanism” Chisholm, M.H.; Macintosh, A.M. J. Chem. Soc. Dalton Trans. 1999, 1205.
• “Four-electron Photochemistry of Dirhodium Fluorophosphine Compounds” Heyduk, A.F.; Macintosh, A.M.; Nocera, D.G. J. Am. Chem. Soc. 1999, 121, 5023.